近期,我?;瘜W與化工學院黃文歡團隊圍繞雜化多孔微納結(jié)構(gòu)的精確構(gòu)造及能量轉(zhuǎn)換存貯性能的調(diào)控方面取得了多項重要進展,連續(xù)在國際頂級期刊Angew Chem.Int. Ed.、Advanced Science、Carbon Energy等期刊上發(fā)表一系列研究論文。
黃文歡課題組與復旦大學車仁超教授合作設(shè)計低CoFe含量的含能MOF(金屬三氮唑)前驅(qū)體,通過三氮唑400度左右的“爆炸”反應可以成功合成具有超低金屬負載、超低密度的具有多級孔結(jié)構(gòu)的CoFe摻雜三維碳海綿材料。實現(xiàn)對金屬原子級分散、材料介電性能、耦合性能、阻抗匹配等的可控調(diào)控。
黃文歡課題組與蘇慶梅教授、揚州大學龐歡教授合作構(gòu)建了離子液體限域MOF(金屬咪唑)/聚合物三維多孔Janus膜,并在充放電循環(huán)過程中原位形成了富含LiF/Li3N的固態(tài)電解質(zhì)界面(SEI)膜。此三維Janus膜具有快速的鋰離子傳輸通道、優(yōu)異的室溫離子電導率(8.17×10-4S cm-1)和高的鋰離子遷移數(shù)(0.82)。該復合電解質(zhì)隔膜具有高熱穩(wěn)定性和機械強度的膜用于固態(tài)Li∥LiFePO4和Li∥NCM-811電池,甚至在軟包電池中均顯示出優(yōu)異的倍率性能和超長的壽命。
文章詳細通過瞬態(tài)吸收光譜監(jiān)測了CZS和CZS @Mo的光生電子動力學行為,證實了Mo電子“陷阱”對電子-空穴復合的抑制作用。此外,DFT理論計算表明Mo原子周圍的高電子密度,反應歷程的吸附自由能解釋了Mo位點的良好催化動力學,證實了Mo原子的電子捕獲效應及其在光催化析氫中的反應機理。本文的研究結(jié)果為可控設(shè)計和制備具有良好應用前景的單原子光催化制氫催化劑提供了重要的理論依據(jù)。該成果發(fā)表于《AngewChem. Int. Ed.》期刊上。
陜西科技大學黃文歡教授、阿卜杜拉國王科技大學張華彬教授,中國石油大學智林杰教授,愛爾蘭三一學院Max García-Melchor教授,北京化工大學于樂教授,清華大學王定勝教授共同總結(jié)了非均相催化劑用于CO2制備羧酸化合物的構(gòu)筑策略,為活化,轉(zhuǎn)化二氧化碳為羧酸等高附加值產(chǎn)物提供了明確的指導和重要參考。本文首先分別從光,電,熱三個方面闡述了相應領(lǐng)域催化的機理過程,羧酸產(chǎn)物的類型和商業(yè)價值,以及目前取得的研究進展。其次從復合催化劑,雜原子參雜,形貌調(diào)控、表面功能化四個方面系統(tǒng)總結(jié)分析了非均相催化劑的合成,調(diào)控策略,強調(diào)了催化位點中配位環(huán)境,電子效應,空間效應等對其活性的影響,以及催化劑結(jié)構(gòu)與活性的內(nèi)在構(gòu)效關(guān)系。最后,展望了CO2制備羧酸化合物面臨的挑戰(zhàn)以及未來的研究方向,為推動CO2的利用和羧酸化學品的可控制備提供了重要的啟示。該成果發(fā)表于《CarbonEnergy》期刊上。
黃文歡課題組與南京理工大學吳凡教授合作,以含能金屬有機骨架為材料,通過燃燒的原位轉(zhuǎn)化工藝,成功制備了具有超高多孔微納結(jié)構(gòu)和均勻分散的CoFe單元的三維磁性分子海綿(表示為CoFe@PCS)。其獨特的框架結(jié)構(gòu)和集成的磁介電元件使其具有高效的微波吸收。在厚度為2.57 mm處,CoFe@PCS的最小反射損耗為?70.10 dB,有效吸收帶寬為8.64 GHz。更重要的是,深入剖析了磁性海綿內(nèi)部的損耗機制和能量耗散,揭示了弛豫主導的介質(zhì)損耗和介電-磁協(xié)同作用。這項工作為高性能吸收體的目標設(shè)計和制造提供了一種巧妙的方法。該成果發(fā)表于《Advanced Composites and Hybrid Materials》期刊上。
張亞男、黃文歡教授,通過主客體效應水熱合成雜多酸摻雜的-銅基金屬有機骨架,通過水熱刻蝕的方法構(gòu)造了POMOF@CoNi-LDH納米片結(jié)構(gòu)。材料類因其超高的比表面積、豐富的電化學活性位點和,作為超級電容器電極材料,在1A·g-1時表現(xiàn)出了333.61 mAh·g-1的高比容量。在混合超級電容器中POMOF@CoNi-LDH/活性炭(AC),能量密度高達80.8 Wh·kg-1、功率密度750.7 W·kg-1。更重要的是,,在10A·g-1條件下充放電5000次后,材料表現(xiàn)出優(yōu)異的電容保持(79%),本文提供了一個高性能儲能電極材料的合成方法及策略。該成果以O(shè)utsideFrontCover發(fā)表于《Chin. J. Chem.》期刊上。
黃文歡教授團隊,通過設(shè)計雙金屬CoNi摻雜的晶態(tài)雜化金屬咪唑框架,利用化學刻蝕及熱處理的方法原位構(gòu)造了超薄的中空CoNi摻雜的碳化鉬球,成功的調(diào)控了材料的介電損耗、磁耦合和阻抗匹配性能。材料在負載量為15wt %時,表現(xiàn)出了最優(yōu)的電磁波吸收性能RLmin=-60.05 dB。該成果受邀發(fā)表于《Chin. J. Chem.》期刊上。
黃文歡,陜西省“科學家+工程師”創(chuàng)新團隊首席科學家、陜西省科技新星,近年來主持國家項目2項、省部級各類科研項目7項、教學項目2項,獲得陜西省高校科學技術(shù)獎一等獎1項,陜西省人才計劃項目2項。在Angew Chem. Int. Ed.、Nano-Micro Letters、Carbon Energy、Matter、Journal of Materials Chemistry A、Energy & Environmental Materials、Chemical Engineering Journal、Materials Chemistry Frontiers、Chemical Communications、Carbon、Journal of Power Sources、Nanoscale、Chemistry-A European Journal、Inorganic Chemistry等國際期刊上發(fā)表SCI論文50余篇,其中受邀撰寫綜述6篇,高被引論文7篇,熱點論文2篇,授權(quán)國家發(fā)明專利4項。曾受邀請在國內(nèi)外學術(shù)會議上作報告10余次,媒體轉(zhuǎn)載相關(guān)研究成果20余次。組織學生參加“挑戰(zhàn)杯”課外學術(shù)科技競賽獲得省級二等獎2項、三等獎1項,獲得陜西省第六屆研究生創(chuàng)新成果展省級一等獎1項,省級創(chuàng)新基金1項;培養(yǎng)研究生獲得“優(yōu)秀畢業(yè)生”、“優(yōu)秀碩士畢業(yè)論文”、“國家獎學金”、“研究生高水平科研成果獎勵”等。
2023年
W. Huang,*X. Zhang, J. Chen, Q. Qiu, Y. Kang, K. Pei, S. Zuo, and R. Che*, High-density Nanopore Confined Vortical Dipoles and Magnetic Domains on Hierarchical Macro/Meso/Micro/Nano Porous Ultra-Light Graphited Carbon for Adsorbing Electromagnetic Wave,Advanced Science, 10.1002/advs.202303217.(2022影響因子:15.1)
X. Zhang, Q. Su*, G. Du, B. Xu, S. Wang, Z. Chen, L. Wang,W. Huang*, H. Pang*, Stabilizing Solid-state Lithium Metal Batteries through In Situ Generated Janus-heterarchical LiF-rich SEI in Ionic Liquid Confined 3D MOF/Polymer Membranes,Angew Chem. Int. Ed.,2023, e202304947.(2022影響因子:16.6)
W. Huang, C. Su, C. Zhu, T. Bo, S. Zuo, W. Zhou, Y. Ren, Y. Zhang, J. Zhang, M. Rueping*, H. Zhang*,Isolated Electron Trap-Induced Charge Accumulation for Efficient Photocatalytic Hydrogen Production,Angew Chem., Int. Ed.,2023, e202304634.(VIP paper)(2022影響因子:16.6)
X. Zhang,W. Huang*,L. Yu, M. García-Melchor, D. Wang, L. Zhi* and H. Zhang* Enabling Heterogeneous Catalysis to Achieve Carbon Neutrality: Directional Catalytic Conversion of CO2into Carboxylic Acids,Carbon Energy,2023,e362.(2022影響因子:20.5)
M. Sun, W. Cao, P. Zhu, Z. Xiong, C. Chen, J. Shu*,W. Huang*, Fan Wu*, Thermally tailoring magnetic molecular sponges through self-propagating combustion to tune magnetic-dielectric synergy towards high-efficiency microwave absorption and Attenuation,Advanced Composites and Hybrid Materials,2023, 6: 54.(2022影響因子:20.1)
H. Ruan, L. Zhang*, S. Li, K. Wang,W. Huang,S. Guo*, Carbon Polyhedra Encapsulated Si Derived from Co-Mo Bimetal MOFs as Anode Materials for Lithium-Ion Batteries,Journal of Materials Science & Technology,2023, 159: 91–98.(2022影響因子:10.9)
Y. Li, X. Jin*, Y. Ma, L. Ma, J Liu, P. Zhu, Z. Deng, H. Zhou, W Chen,W. Huang*,Functional decoration on a regenerable bifunctional porous covalent organic framework probe for the rapid detection and adsorption of copper ions,Rare Metals,In press.(2022影響因子:8.8)
Y. Zhang, J. Chen, F. Razq, C. Su, X. Hou,W. Huang*,and H. Zhang*, Polyoxometalate-incorporated host-guest framework derived layered double hydroxide composites for high-performance hybrid supercapacitor,Chinese Journal of Chemistry,2023,41, 75-82.(雜志封面Outside Front Cover)(2022影響因子:5.4)
X. Yang, W. Gao, J. Chen, X. Lu, D. Yang, Y. Kang, Q. Liu, Y. Qing, andW. Huang*, Co-Ni Electromagnetic Coupling in Hollow Mo2C/NC Sphere for Enhancing Electromagnetic Wave Absorbing Performance,Chinese Journal of Chemistry,2023, 41, 64-74.(邀稿,2022影響因子:5.4)
J. Gu, Q. An, J. Chen, Y. He,W. Huang*, Preparation and Responsive Performance study of AuNPs/RGO-MoO2/GCE Composite Modified Electrodes based on its High Sensitivity to Acetaminophen and Dopamine,Inorganic Chemistry Communications,2023, 147, 110282.(2022影響因子:3.8)
Y.Kang, X. Sun, Y. Wang, Y. Zhang, W. Huang*,Design and Synthesis of Copper-Based Simulated Enzyme Induced by Nitrogen Oxidation Ligand and Study of Its Activity.Chinese Journal of Structural Chemistry,2023, 42, 100046.(邀稿,2022影響因子:2.2)
2022年
W. Huang*, Q. Qiu, X. Yang, S. Zuo, J. Bai, H. Zhang*, K. Pei and R. Che*, Ultrahigh Density of Atomic CoFe-Electron Synergy in Noncontinuous Carbon Matrix for Highly Efficient Magnetic Wave Adsorption.Nano-Micro Letters,2022, 14(1): 96.(2022影響因子:26.6)
C. Feng, Y. Ren, F. Razq,W. Huang*, H. Zhang*, An innovative and ingenious strategy to construct single-atom catalyst for photocatalytic methane conversion,Matter,2022,5, 3086–3111.(2022影響因子:18.9)
W. Huang, T. Bo, S. Zuo, Y. Wang, J. Chen, S. Ould‐Chikh, Y. Li, W. Zhou*, J. Zhang, H. Zhang*, Surface decorated Ni sites for superior photocatalytic hydrogen production,Susmat,2022, 1-10.(邀稿,2022影響因子:28.4)
W. Huang*, W. Gao, S. Zuo, L. Zhang, K. Pei, P. Liu and R. Che*, and H. Zhang*, Hollow MoC/NC Sphere for Electromagnetic Wave Attenuation: Direct Observation of Interfacial Polarization on Nanoscale Hetero-interfaces.Journal of Materials Chemistry A,2022, 10: 1290-1298.(雜志封面Outside Front Cover)(高被引論文)(2022影響因子:11.9)
P. Li, Z. He, X. Li,W. Huang*, and X. Lu*, Fullerene-Intercalated Graphitic Carbon Nitride as a High-Performance Anode Material for Sodium Ion Batteries.Energy & Environmental Materials,2022, 5: 608–616.(邀稿,2022影響因子:15)
Y. Zhang, J. Chen, C. Su, K. Chen, H. Zhang, Y. Yang,W. Huang*, Enhanced ionic diffusion interface in hierarchical metal-organic framework@layered double hydroxide for high-performance hybrid supercapacitors,Nano Research,2022, 15(10), 8983-8990.(2022影響因子:9.9)
W. Huang*, J. Chen, W. Gao, L. Wang, P. Liu*, Y. Zhang, Z. Yin, Y. Yang, “Host-Guest” crystalline Mo/Co-framework induced phase-conversion of MoCx in carbon hybrids for regulating absorption of electromagnetic wave,Carbon,2022, 197: 129-140.(2022影響因子:10.9)
W. Huang*, S. Wang, X. Yang, X. Zhang, Y. Zhang, K. Pei, R. Che*, Temperature induced transformation of Co@C nanoparticle in 3D hierarchical core-shell nanofiber network for enhanced electromagnetic wave adsorption,Carbon,2022, 195: 44-56.(2022影響因子:10.9)
W. Huang*, Z. Chen, H. Wang, L. Wang, H. Zhang, and H. Wang, Sponge-like hierarchical porous carbon decorated by Fe atoms for high-efficient sodium storage and diffusion.Chemical Communications,2022, 58(28), 4496-4499.(2022影響因子:4.9)
Y. Zhang, C. Su, J. Chen,W. Huang*and R. Lou, Recent progress of transition metal-based biomass-derived carbon composites for supercapacitor,Rare metals,2022,10.1007/s12598-022-02142-7.(2022影響因子:8.8)
Z. He, Z. Zhou, P. Wei, T. Xu, J. Han, K. Huang, K. Guo*,W. Huang*, T. Akasaka, X. Lu*, Fullerene-Derived Porous and Defective N-Doped Carbon Nanosheets as Advanced Trifunctional Metal-Free Electrocatalysts,Chemistry - An Asian Journal,2022, 202200994.(2022影響因子:4.1)
2021年
W. Huang*, X. Li, X. Yang*, H. Zhang, P. Liu, Y. Ma, and X. Lu, CeO2-embedded mesoporous CoS/MoS2as highly efficient and robust oxygen evolution electrocatalyst.Chemical Engineering Journal,2021, 420: 127595.(2022影響因子:15.1)
W. Huang*, X. Li, X. Yang*, X. Zhang, H. Wang, The recent progress and perspectives on the metal- and covalent- organic frameworks based solid-state electrolytes for lithium-ion batteries.Materials Chemistry Frontiers,2021, 5 (9): 3593-3613.(邀稿,2022影響因子:7.0)
W. Huang*, X. Li, X. Yang, H. Zhang, F. Wang, J. Zhang*. High-Efficient Electrocatalyst for Overall Water Splitting: Mesoporous CoS/MoS2with Hetero-Interface.Chemical Communications,2021, 57: 4847-4850.(2022影響因子:4.9)
W. Huang*, Q. Li, D. Yu, Y. Tang, D. Lin, F. Wang*, J. Zhang*, Hybrid Zeolitic Imidazolate Frameworks for Promoting Electrocatalytic Oxygen Evolution via a Dual-Site Relay Mechanism.Inorganic Chemistry,2021, 60(5): 3074-3081.(2022影響因子:4.6)
X. Yang, Y. Yan, W. Wang, Z. Hao, W. Zhang*,W. Huang*, Y. Wang, A 2-Fold Interpenetrated Nitrogen-Rich Metal–Organic Framework: Dye Adsorption and CO2Capture and Conversion.Inorganic Chemistry.2021,60(5): 3156-3164(2022影響因子:4.6)
W. Huang*, X. X. Zhang and Y. N. Zhao, Recent progress and perspectives on the structural design on metal-organic zeolite (MOZ) frameworks.Dalton Transactions,2021, 50: 15-28.(邀稿,2022影響因子:4.0)
Y. Zhang, J. Chen, C. Su,W. Huang*, A multifunctional cadmium-based metal-organic framework from a tricarboxylate ligand showing sensing and sensitization.Journal of Solid State Chemistry,2021, 302: 122407.(2022影響因子:3.3)
C. Zuo, F. Zhao, Z. Tang, L. Zhang, Q. Niu, G. Cao, L. Zhao,W. Huang*, and P. Zhao*, Bi2O3gated Fe3O4@ZrO2core/shell drug delivery system for chemo/ionic synergistic therapeutics.Journal of Solid State Chemistry,2021, 303: 122489.(2022影響因子:3.3)
2020年
P. Liu*, S. Gao, Y. Wang, Y. Huang, W. He,W. Huang, J. Luo, Carbon nanocages with N-doped carbon inner shell and Co/N-doped carbon outer shell as electromagnetic wave absorption materials,Chemical Engineering Journal,2020, 381: 122653.(高被引論文)(2022影響因子:15.1)
T. Xu, W. Shen,W. Huang*, and X. Lu*. Fullerene Micro/Nanostructures: Controlled Synthesis and Energy Applications.Materials Today Nano,2020, 11:100081.(邀稿,2022影響因子:10.3)
W. Huang*, X. Zhang, Y. Zhao, J. Zhang, and P. Liu*, Hollow N-doped carbon polyhedrons embedded Co and Mo2C nanoparticles for high-efficiency and wideband microwave absorption.Carbon,2020, 167: 19-30.(高被引論文,熱點論文)(2022影響因子:10.9)
P. Liu*, S. Gao, Y. Wang, F. Zhou, Y. Huang,W. Huang*, and N. Chang, Core-shell Ni@C encapsulated by N-doped carbon derived from nickel-organic polymer coordination composites with enhanced microwave absorption.Carbon,2020, 170: 503-516.(高被引論文,熱點論文)(2022影響因子:10.9)
P. Liu*, S. Gao,W. Huang*, J. Ren, D. Yu, and W. He, Hybrid zeolite imidazolate framework derived N-implanted carbon polyhedrons with tunable heterogeneous interfaces for strong wideband microwave attenuation.Carbon,2020, 159: 83-93.(高被引論文)(2022影響因子:10.9)
W. Huang*, X. Li, D. Yu, X. Yang, L. Wang, P. Liu, and J. Zhang, CoMo-bimetallic N-doped porous carbon materials embedded with highly dispersed Pt nanoparticles as pH-universal hydrogen evolution reaction electrocatalyst.Nanoscale,2020, 12: 19804-19813.(2022影響因子:6.7)
T. Xu, D. Yu, Z. Du,W. Huang*, and X. Lu, Two-Dimensional Mesoporous Carbon Materials Derived from Fullerene Microsheets for Energy Applications.Chemistry-A European Journal,2020, 26: 10811.(2022影響因子:4.3)
K. Zhong, R. Yang, W. Zhang*, Y. Yan, X. Gou,W. Huang*,and Y.-Y. Wang, Zeolitic Metal Cluster Carboxylic Framework for Selective Carbon Dioxide Chemical Fixation through the Superlarge Cage.Inorganic Chemistry,2020, 59: 3912-3918.(2022影響因子:4.6)
Y. Zhang*,Y. Zhang, L. Li, J. Chen, P. Li,W. Huang*. One-step in situ growth of high-density POMOFs films on carbon cloth for the electrochemical detection of bromate.Journal of Electroanalytical Chemistry,2020, 861: 113939.(2022影響因子:4.5)
(核稿:黃文歡 編輯:趙誠)